Cross dehydrogenative coupling of N-aryltetrahydroisoquinolines (sp3 C-H) with indoles (sp2 C-H) using a heterogeneous mesoporous manganese oxide catalyst

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Cross dehydrogenative coupling of N-aryltetrahydroisoquinolines (sp3 C-H) with indoles (sp2 C-H) using a heterogeneous mesoporous manganese oxide catalyst

Green Chem., 2017, Advance Article
DOI: 10.1039/C7GC01919J, Communication
B. Dutta, V. Sharma, N. Sassu, Y. Dang, C. Weerakkody, J. Macharia, R. Miao, A. R. Howell, S. L. Suib
We disclose a novel, heterogeneous catalytic approach for selective coupling of C1 of N-aryltetrahydroisoquinolines with C3 of indoles in the presence of mesoporous manganese oxides.

Cross dehydrogenative coupling of N-aryltetrahydroisoquinolines (sp3 C–H) with indoles (sp2 C–H) using a heterogeneous mesoporous manganese oxide catalyst

 Author affiliations

Biswanath Dutta

Ph.D Candidate

Chemistry


B.Sc. Chemistry, University of Calcutta, India, 2011

M.S. Chemistry, IIT Bombay, India, 2013

Group Member Since 2013

Research Area: Material synthesis, Catalysis

Image result for University of Connecticut S. L. Suib

Steven Suib

Professor

Email steven.suib@uconn.edu
Phone (860) 486-2797
Fax (860) 486-2981
Mailing Address University of Connecticut
Department of Chemistry
55 N. Eagleville Rd
Storrs, CT 06269
Office Location CHEM A-313

Abstract

We disclose a novel, heterogeneous catalytic approach for selective coupling of C1 of N-aryltetrahydroisoquinolines with C3 of indoles in the presence of mesoporous manganese oxides. Our work involves a detailed mechanistic investigation of the reaction on the catalyst surface, backed by DFT computational studies, to understand the superior catalytic activity of manganese oxides.

 

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